MERCK 807250.0250 Phenylenediamine for Synthesis
| Description |
|---|
| Catalogue Number | 807250 |
| Description | Phenylhydrazine |
| Product Information |
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| CAS number | 100-63-0 |
| EC index number | 612-023-00-9 |
| EC number | 202-873-5 |
| Hill Formula | C₆H₈N₂ |
| Chemical formula | C₆H₅NHNH₂ |
| Molar Mass | 108.14 g/mol |
| HS Code | 2928 00 90 |
| Structure formula Image |
| Quality Level | MQ200 |
| Applications |
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| Application | Phenylhydrazine for synthesis. CAS 100-63-0, EC Number 202-873-5, chemical formula C₆H₅NHNH₂. |
| Physicochemical Information |
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| Boiling point | 244 °C (1013 hPa) |
| Density | 1.099 g/cm3 |
| Explosion limit | 1.1 %(V) |
| Flash point | 89 °C |
| Ignition temperature | 195 °C |
| Melting Point | 19 °C |
| Vapor pressure | 1.35 hPa (60 °C) |
| Solubility | 145 g/l |
| Toxicological Information |
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| LD 50 oral | LD50 Rat 188 mg/kg |
| Safety Information according to GHS |
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| Hazard Pictogram(s) | |
| Hazard Statement(s) | H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled.H315: Causes skin irritation.H317: May cause an allergic skin reaction.H319: Causes serious eye irritation.H341: Suspected of causing genetic defects.H350: May cause cancer.H372: Causes damage to organs through prolonged or repeated exposure.H400: Very toxic to aquatic life. |
| Precautionary Statement(s) | P273: Avoid release to the environment.P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection.P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor.P302 + P352 + P312: IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/doctor if you feel unwell.P304 + P340 + P311: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor.P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| Signal Word | Danger |
| RTECS | MV8925000 |
| Storage class | 6.1A Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials |
| WGK | WGK 3 highly hazardous to water |
| Disposal | 9Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535). |
| Safety Information |
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| Categories of danger | carcinogenic, toxic, irritant, sensitizing, dangerous for the environment, mutagenic |
| Storage and Shipping Information |
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| Storage | Store below +30°C. |
| Transport Information |
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| Declaration (railroad and road) ADR, RID | UN 2572, 6.1, II |
| Declaration (transport by air) IATA-DGR | UN 2572, 6.1, II |
| Declaration (transport by sea) IMDG-Code | UN 2572, 6.1, II |
| Specifications |
|---|
| Assay (HClO₄) | ≥ 97.0 % |
| Density (d 20 °C/ 4 °C) | 1.096 - 1.099 |
| Identity (IR) | passes test |
| Due to its specific melting range the product may be solid, liquid, a solidified melt or a supercooled melt. |
| Global Trade Item Number |
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| Catalogue Number | GTIN |
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| 8072500005 | 04022536394442 |
| 8072500250 | 04022536394459 |
| 8072501000 | 04022536394466 |
