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SD.M.106432.5000
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MERCK 106432.5000 Tri-Sodium Citrate Dihydrate Cryst. Emprove

CAS #EC NumberHill FormulaMolar MassGrade Value
6132-04-3200-675-3C₆H₅Na₃O₇ * 2 H₂O294.10 g/molPh Eur,BP,JP,USP,E 331
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Description
Catalogue Number106432
SynonymsTrisodium Citrate, Sodium Citrate, Dihydrate

Product Information
CAS number6132-04-3
EC number200-675-3
GradePh Eur,BP,JP,USP,E 331
Hill FormulaC₆H₅Na₃O₇ * 2 H₂O
Molar Mass294.10 g/mol
HS Code2918 15 00
Structure formula Image
Quality LevelMQ500
Physicochemical Information
Melting Point300 °C (anhydrous substance)
pH value7.5 - 9.0 (50 g/l, H₂O, 25 °C)
Bulk density600 kg/m3
Solubility720 g/l
Toxicological Information
LD 50 oralLD50 Rat > 8000 mg/kg
Safety Information according to GHS
Storage class10 - 13 Other liquids and solids
WGKWGK 1 slightly hazardous to water
Disposal3Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. For solid residues use container C.
Storage and Shipping Information
StorageStore at +2°C to +30°C.
Transport Information
Declaration (railroad and road) ADR, RIDKein Gefahrgut
Declaration (transport by air) IATA-DGRNo Dangerous Good
Declaration (transport by sea) IMDG-CodeNo Dangerous Good
Specifications
Assay (Perchloric acid titration, calc. on anhydrous substance (Ph Eur))99.0 - 101.0 %
Assay (Perchloric acid titration, previously dried substance) (JP/USP)99.0 - 100.5 %
Identity (Na)passes test
Identity (Citrate)passes test
Identity (reaction upon ignition)passes test
Appearancewhite to almost white crystals
Appearance of solution (100 g/l, CO₂-free water)clear and colorless
Acidity or alkalinitypasses test
pH (50 g/l CO₂-free water)7.5 - 8.5
Chloride (Cl)≤ 50 ppm
Sulfate (SO₄)≤ 150 ppm
Al (Aluminium)≤ 5 ppm
As (Arsenic)≤ 1 ppm
Hg (Mercury)≤ 1 ppm
Pb (Lead)≤ 1 ppm
Oxalate (as C₂H₂O₄)≤ 100 ppm
Tartrate (C₄H₄O₆)passes test
Residual solvents (ICH (Q3C))excluded by manufacturing process
Readily carbonisable substancepasses test
Water (according to Karl Fischer)11.0 - 13.0 %
Loss on drying (180 °C, 18 h)10.0 - 13.0 %
Elemental impurity specifications have been set considering ICH Q3D (Guideline for Elemental Impurities). Class 1-3 elements are not likely to be present above the ICH Q3D option 1 limit, unless specified and indicated (*).
Corresponds to Ph. Eur., BP, JP, USP, E 331Conforms to the purity criteria on food additives according to the current European Commission Regulation.
Corresponds to Ph. Eur., BP, JP, USP, E 331Conforms to the purity criteria on food additives according to the current European Commission Regulation.
Global Trade Item Number
Catalogue NumberGTIN
106432100004022536076621
106432500004022536076645
106432902904022536940090
106432905204027269971052